Anmol Chemicals is the pioneer manufacturers of Sodium Fluoride, Pharmaceutical Excipients Fragrance & Flavor chemicals in India. We offer Halal and Kosher Sodium Fluoride made in an ISO9001:2008, ISO22000:2005 (FSSC22000) and cGMP certified facility. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in UAE, Europe, Africa, USA, China and has several associated manufacturing facilities spread across India. All the Information on Physics, Chemistry, Applications, Uses and Technology on Manufacture of Sodium Fluoride is in these pages.

The units have one or more of the certifications like FDA GMP, ISO 9001, ISO 22000, HACCP, REACH, Kosher & Halal

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Sodium Fluoride SDS GHS, MSDS Sheet

Specifications of Sodium Fluoride

Sodium Fluoride SDS GHS, MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: NaF
CAS No.: 7681-49-4
EINECS EC Number: 231-667-8
Molecular Weight: 41.99
Chemical Formula: NaF
Intended Use: Industrial Manufacturing

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 3 (H301)
Skin corrosion/irritation Category 2 (H315)
Serious eye damage/eye irritation Category 2A (H319)

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

GHS Label Elements
Toxic
Toxic

Signal Words: Danger

Hazard statements:
H301 Toxic if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.

Precautionary statements:
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store in a closed container.
P501 Dispose of contents/ container to an approved waste disposal plant
Other Hazards: AUH032 Contact with acids liberates very toxic gas.
Poisons Schedule (SUSMP): S6 Poison.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
T; R25
R32
Xi; R36/38
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Sodium Fluoride
CAS No.: 7681-49-4
EINECS EC Number: 231-667-8

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Contact a poison control center or physician for treatment advice. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Non-flammable.
Flash Points: Not applicable.
Products of Combustion: During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Hydrogen fluoride, Sodium oxides can be formed.
Fire: Sodium Fluoride is not considered to be a fire hazard.
Fire Extinguishing Media: Use water spray or fog for cooling exposed containers. Fine water spray, normal foam, dry agent (carbon dioxide, dry chemical powder) can be used. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.

7. Handling and Storage

Toxic if swallowed. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: ACGIH TLV, OSHA PEL & NIOSH IDLH Permissible 2.5 mg/m3 TWA (dust and mist, as F).
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Sodium Fluoride is transparent or white powder or crystals.
Odor: It is odorless.
Solubility: It is freely soluble in water.
pH: 7 to 10 for 10% solution.
Density: 2.76 g/mL at 16C
Molecular formula
: NaF
Molecular weight: 41.99
Boiling Point: 1695C.
Melting Point: 996C.

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxides of sodium and hydrochloric acid fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Acids.
Conditions to Avoid: Incompatibles and moisture. Avoid Heat, Moisture & incompatibles

11. Toxicological Information

Toxicity data
LD50 Oral - Rat - female - 148,5 mg/kg
LD50 Intravenous - Rat - 26 mg/kg
LD50 oral - Rabbit - 200 mg/kg
Carcinogenic Effects: Not known to be a carcinogen by IARC NTP ACGIH OSHA.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Toxicity to fish: mortality NOEC- Cyprinodon variegatus (sheepshead minnow) - 500 mg/l - 96h
LC50 - Oncorhynchus mykiss (rainbow trout) - 200 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 98 mg/l - 48 h
Environmental Fate: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

This product is a registered pesticide. Pesticide wastes are acutely hazardous. Improper disposal of excess pesticides, spray mixtures, or rinsate is a violation of Law. Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

US DOT Classification:
UN No: 1690
Transport Hazard Class: 6.1 Toxic
Packing Group: III
Proper Shipping Name or Technical Name: SODIUM FLUORIDE, SOLID
Canada TDG Classification:
UN No: 1690
Transport Hazard Class: 6.1 Toxic
Packing Group: III
Proper Shipping Name or Technical Name: SODIUM FLUORIDE, SOLID
IATA
UN No: 1690
Transport Hazard Class: 6.1 Toxic
Packing Group: III
Proper Shipping Name or Technical Name: SODIUM FLUORIDE, SOLID
ADR/RID:
UN No: 1690
Transport Hazard Class: 6.1 Toxic
Packing Group: III
Proper Shipping Name or Technical Name: SODIUM FLUORIDE, SOLID

15. Regulatory Information

USA:
TSCA 12 (b)
: Not applicable.
SARA 311/312: Acute Health Hazard.
SARA 313 Components: Not applicable

Canada - WHMIS: D1B Toxic materials, D2A Very toxic materials, D2B Toxic materials.

16. Other Information

EINECS EC Number: 231-667-8
H301 = Toxic if swallowed.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
T = Toxic
Xi = Irritant
R25 = Toxic if swallowed
R32 = Contact with acids liberates very toxic gas
R36/38 = Irritating to eyes and skin

Disclaimer:
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Our company provides this Sodium Fluoride MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Sodium Feredetate manufacturers at:

Anmol Chemicals
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564 - FAX: 91-22-23728264

e-mail: anmolc@mtnl.net.in

ISO9000

Exports to USA, Canada, UAE, Dubai, South Africa, Tanzania, Kenya, Nigeria, Egypt, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Europe Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan,etc.

Copyright and Usual Disclaimer is Applicable. 15 March, 2016